Page 30 - Plastics News August - 2023
P. 30

A Better Approach to Biodegradation of Polymer Waste

                                                                                 to demonstrate  this circular loop of
                                                                                 making polyester plastic, and not just
                                                                                 theorize  that it could happen. They
                                                                                 went  through  the  steps  of  first  de-
                                                                                 grading samples to the starting mono-
                                                                                 mers and then re-forming a polyester
                                                                                 plastic. There is not enough informa-
                                                                                 tion available to assess its economic
                                                                                 viability they may well be applying for
                                                                                 patents as I write this but my initial re-
                                                                                 action is not too optimistic about this
              arnessing enzymes  to depolym-  second, less-common approach uses  being a commercially viable technol-
          Herize waste polyester  and re-    biochemicals,  specifically  enzymes  ogy. If you think about the “normal”
          using the material to make new prod-  made by “bugs,” to degrade the plas-  recycling loop — make a product, sell
          ucts has been shown to work. But is it  tic. (Enzymes are protein-based cata-  it, use it, retrieve it, and then repro-
          economically viable?               lysts that speed up a specific chemical  cess  it  into  a new  product — these
          There are hundreds of researchers fo-  reaction  without  being  consumed  in  degradation and repolymerization
          cused on applying biological solutions   it.)                          steps add another operation (or two).
          to plastic waste. Their efforts can be  Researchers at UT-Austin have had  For what? The researchers started
          divided into two approaches. The first  some notable success with the sec-  with PET and ended up with PET af-
          uses “bugs” — microbes, fungi, and  ond approach recently. They  used  terwards. What was gained? Or look-
          so forth — to eat the plastic, while the  synthetic biology to create an enzyme  ing at it from another direction: What
          second, less-common approach uses  that degrades polyester back into its  problem was solved? This is just add-
          biochemicals,  specifically  enzymes  starting materials. In other words, the  ing extra steps.
          made by “bugs,” to degrade the plas-  enzymes are breaking the ester bond   Except if I think about this a bit more,
          tic. (Enzymes are protein-based cata-  that  makes  polyester.  The  starting   Post-consumer waste in the recycling
          lysts that speed up a specific chemical  chemicals can be recovered and then   stream can be heavily contaminated
          reaction  without  being  consumed  in  turned back into new polyester.  due to poor separation from other
          it.)                               Enzymes tuned to specific chemi-    recyclables, dirt, food,  and other
          Researchers at UT-Austin have had  cal reactions                       contaminants. Because of this, I’ve al-
          some notable success with the sec-  This  stands  in  stark  contrast  to  the   ways had high respect for recyclers.
          ond approach recently. They  used   aforementioned first approach, which   They’re dealing with a messy feed
          synthetic biology to create an enzyme   involves letting microbes and fungi de-  that I’m glad I never had to. I’ve ex-
          that degrades polyester back into its   grade the material. Such degradation   perienced plenty of bad days just try-
          starting materials. In other words, the   is not as controlled, and the result is a   ing to process regrind, a feed stream
          enzymes are breaking the ester bond   seriously degraded product that isn’t   that  never  left the  plant. To try  and
          that  makes  polyester.  The  starting   much good for anything else. This is   work with  whatever  garbage is sent
          chemicals can be recovered and then   what happens to compostable plas-  as recyclables scares me plenty. This
          turned back into new polyester.    tics — you get compost that can’t be   technology might make that easier in
          There are hundreds of researchers fo-  turned into plastic. By contrast, en-  the future.
          cused on applying biological solutions  zymes are tuned to specific chemical  Since the  enzymatic  reaction is so
          to plastic waste. Their efforts can be  reactions  and  cannot  influence  any  specific,  it  should  be  possible  that  it
          divided into two approaches. The first  other reactions.               could find and degrade the polyester
          uses “bugs” — microbes, fungi, and   The  researchers  were  actually  able   — and just the polyester — in a pile
          so forth — to eat the plastic, while the                               of contaminated plastic.




          30   PLASTICS NEWS                                                                           August 2023
          30 PLASTICS NEWS
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