Page 41 - Plastics News February 2020
P. 41

FeAtures




          primarily by the screw speed and head pressure, and   noted—will save a lot of time and scrap. Even if designed
          generally to a lesser extent by the barrel temperature.   for the same polymer, the screws are engineered for a
          However, the practice of adiabatic extrusion almost always   certain melt temperature at a specific speed, which is
          helps stabilize the whole process. Adiabatic extrusion   usually at or near their capacity. Therefore, if you run
          is seeking temperature settings where there is minimal   one screw at one-third speed, another at two-thirds
          thermal cycling of the barrel temperatures—i.e. no heat,   speed and the third at full speed, they will produce
          no cooling.                                           substantially different melt temperatures. Since polymers
                                                                are poor conductors of heat and a good coextrusion block
          The shear-thinning effect                             is designed to prevent intermixing of the layers, the layers
          The shear-thinning effect is different for every polymer   will maintain their temperature through the coextrusion
          and grade.  The individual curves are also offset up   block and will thermally homogenize only in the die itself.
          or  down  as  the  temperature  decreases  or  increases,   It can take considerable time for the layers to stabilize
          respectively. How the shear rate and temperatures     at a single temperature. For example, in the case of the
          affect polymer viscosity in the tooling can result in   thin HDPE cast film coex line cited above, it was necessary
          considerable variations in pressure drop through the die.         to run all three extruders to prevent degradation in the
          Polymer viscosity mismatch leads primarily to distortion   coextrusion block of resin from any extruders not being
          of the layers. However, excessive shear in any of the   operated.
          layers can lead to melt fracture, usually corrected by
          raising the melt temperature—but that results in having   Advantages Of Co-extrusion:
          to raise the temperature of each layer. Non-uniformity   ●   High quality mono-layer extrusion coatings in larger
          of melt temperature causes zig-zag patterns or wave       varieties of line speeds and widths
                                                                ●   Use of lower cost materials for filling purpose, assists
                                                                    in saving on the amount of qualitative resins
                                                                ●   Capability  of  making  multi-layer  as  well  as  multi-
                                                                    functional structures that too in a single pass
                                                                ●   Reduction in the number of steps required in general
                                                                    extrusion process
                                                                ●   Provides  targeted  performance  with  the  use  of
                                                                    definite polymers in particular layers
                                                                ●   Reduction in setup and trim scrap
                                                                ●   Potential for use of a recycle layer
                                                                Disadvantages Of Co-extrusion:
                                                                ●   Minor  differences  in  physical  properties  are
                                                                    responsible for making a combination desirable, but
          effects in the sheet, so the most stable system possible   these differences are also responsible for making the
          is needed. Die swell varies between polymers and is a     combination incompatible
          function of temperature and shear rate for a particular
          polymer and may require changes in the layer thickness   ●   For  this  process,  polymers  must  have  similar  melt
          to meet profitable operating levels. These are meant as   viscosities to sustain a laminar flow. All the viscosity
          words of caution to those not experienced in coextrusion   differences may be more or less tolerable, according
          processing and do not apply in monolayer extrusions       to the material location inside the composite
          unless supplemental adapters and dies are also part of the   structure along with the layer's thinness
          equipment. With additional adapters and dies you can shut   ●   Requires  more  sophisticated  extruder  and  its
          off and disconnect any extruders not required, as well as   operator. This implies extra maintenance cost of the
          change or eliminate the feedblock or multi-manifold die.   equipment.
          Additionally, proper training of the operating personnel   ●   Demands considerable planning as well as forethought
          on how to deal with the issues noted—as well as some not   in the system design



                                                                                 41  Februar y 2020     Plastics News
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