Page 47 - Plastics News January 2021
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teChnoLogy



          Breaking down Plastics into their constituents



             esearchers from                                    Recycling  Technologies  to  collaborate  with  NiTech,
          Rt he   Universit y                                   a leading authority and expert on continuous processing,
          of Bath’s Centre for                                  the Centre for Sustainable and Circular  Technologies
          Sustainable and Circular                              (CSCT) at the University of Bath and Optimal Industrial
          Technologies (CSCT)                                   Automation, a leading specialist in the automation
          have linked up with                                   of manufacturing systems to optimise production
          Recycling Technologies,                               processes.The project examined the feasibility of
          also in the UK, to develop                            incorporating  NiTech’s  Oscillating  Baffle  Reactor  (OBR)
          a method of chemically                                into the existing elements within Recycling Technologies
          breaking down mixtures                                pyrolysis machine to enhance the quality of Plaxx® to
          of plastics into their                                steam-cracker ready feedstock, thus avoiding the need for
          constituents, which                                   pre-treatment in advance to the manufacture of new plastic.
          can  then be  used  to                                At the University of Bath, Professor Matthew Davidson,
          manufacture new plastics. The company has announced   Dr Alfred Hill, Dr Simon Freakley, Dr Ulrich Hintermair
          it has completed the first phase of a project funded by   and Professor Marcelle McManus from the CSCT have
          the Small Business Research Initiative (SBRI) from UK   all  been  involved  in  the  project.  Matthew  Davidson,
          Research and Innovation to enhance the efficiency of its   Whorrod Professor of Sustainable Chemical Technologies
          chemical recycling process by hydrogenating Plaxx®, a   and Director of the CSCT said, “We are delighted to have
          recycled feedstock which can be used to manufacture   been a key part of this exciting project working with a
          new plastic. The project also investigated automation of   range of specialist companies on the problem of plastics
          the recycling process.The SBRI project funding allowed   sustainability.

         Flashing plastic ash completes recycling



             ice University                                     in 2019, pyrolyzed ash turns into turbostratic graphene.
         Rscientists have                                       That has weaker attractive interactions between the
         turned their attention                                 flakes, making it easier to mix them into solutions. Last
         to Joule heating of the                                October, the Tour lab reported on a process to convert
         material, a byproduct                                  waste plastic into graphene. The new process is even
         of plastic recycling                                   more specific, turning plastic that is not recovered by
         processes.  A  strong                                  recycling into a useful product. "This work enhances the
         jolt of energy flashes                                 circular economy for plastics," Tour said. "So much plastic
         it into graphene.The                                   waste is subject to pyrolysis in an effort to convert it
         technique by the lab of                                back to monomers and oils.  The monomers are used
         Rice chemist James Tour                                in repolymerization to make new plastics, and the oils
         produces turbostratic                                  are used in a variety of other applications. But there is
         graphene flakes that                                   always a remaining 10% to 20% ash that's valueless and
         can be directly added                                  is generally sent to landfills. "Now we can convert that
         to other substances                                    ash into flash graphene that can be used to enhance the
         like films of polyvinyl                                strength of other plastics and construction materials," he
         alcohol (PVA) that better resist water in packaging and   said.  Adding as little as 0.1% of graphene increases the
         cement paste and concrete, dramatically increasing their   amount of strain the PVA composite can handle before
         compressive strength.The research appears in the journal   failure by up to 30%, they reported. It also significantly
         Carbon. Like the flash graphene process the lab introduced   improves the material's resistance to water permeability.



                                                                                 47    Januar y 2021     Plastics News
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