Page 33 - Plastics News July 2018
P. 33

FeAtures



          Injection Molding: Safety First—Know the Compatibility of Different

          Resins

          Certain materials don’t play well together when mixed. So it’s best not to. Here are some guidelines.
                                                                                                JOHN BOZZELLI


             ecause of the growth of the plastics industry, there has   walls, etc. The gases produced upon resin decomposition
          Bbeen an uptick in number of new hires for processing   generate extreme pressures, which can and do blow
          plastics  over  the  last  few  years.  With  new  employees   injection molding machine barrels into shrapnel. The
          comes the challenge of training—not only on company   accompanying photo shows the front zone of a machine
          policies and processing duties, but on safety. With that in   barrel that blew into pieces. Imagine the damage if it had
          mind, this column will focus on a topic I feel does not get   hit someone! This may not happen often, but it does occur,
          sufficient attention. In fact, it is a topic on which most of   and you need to be aware its possibility. The question
          us do not have all the details needed. In my experience,   of resin compatibility is not well publicized and rarely
          searches on  the  internet certainly  proved inadequate.   comes up out on the shop floor. So, any time you purge
          That topic is the mixing of different resins in the barrel,   to change resins, you need to ask the question: Are these
          hot runners, and hot tips.                            resins compatible or do they react like PVC and acetal?
          This is an issue whenever you change jobs to a new mold   I’ve developed a list of plastics that I know could possibly
          with a different resin. Are the two resins compatible or   react with one another. My bet is there are others that I
          do  they  react  with  one  another?  No  matter  how  hard   do not know about. If you know of any others, please let
          you try to purge the previous resin from the system,   me know.

                                                                Here’s my list:
                                                                •   Acetal with PVC or CPVC.

                                                                •   Ionomer with acetal, PVC or CPVC.

                                                                •   TPV with acetal, PVC or CPVC.
                                                                If  the  same  machine  barrel  and  screw  must  process
                                                                both these resins, disassemble and clean them properly
                                                                before resuming processing. Even small residues can be
                                                                hazardous.

                                                                Of course, safety in injection molding extends beyond
          small amounts will remain on the screw flights. Purging   material compatibility. High temperatures and pressures
          compound may help, but even a small residual amount   of 20,000 to 45,000 psi are needed to melt and inject
          of the previous resin can provide a catalytic effect. For   plastic into complex shapes. While these machines are
          example, if you accidently mix acetal (POM) with PVC, you   built robustly to handle these temperatures and pressures,
          and the rest of the people on the shop floor will have an   it’s best take a serious look at the equipment on a regular
          extremely unpleasant emotional and physical experience.   basis and not assume all is OK. Do you review the machine/
          Small amounts of either of these two resins catalyzes the   mold upon startup or during production to make sure these
          decomposition of the other polymer to gases.          pressures and temperatures do not reach out and touch

          The resulting acrid odor is well known to Crusty Sr., my   you or a coworker? For example, does the nozzle tip mate
          archetype of the grizzled processor. Find someone who has   properly with the sprue bushing? Is a temperature zone
          some experience processing PVC or acetal; ask about his   overriding? Are you sure all is OK before you look down
          or her experiences. You will hear true stories of hoppers   into the hopper?
          being blown to and through roofs, endcaps blown through   Who is responsible for your safety? Look in the mirror.



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