Page 39 - Plastics News May 2018
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FeAtures
                  FEATURES



          moulding technology using co-extruded composite       As with increasing stiffness, the impact resistance usually
          pellets or bicomponent PP fibres as raw materials.7, 8  deteriorates; it is important to investigate this property
                                                                of the SR-PPCs with increased modulus.  The impact
          Figure 5
                                                                resistance of the injection moulded ePP and SR-PPC sheets
                                                                was compared using instrumented falling weight impact
                                                                tests. Based on the fractograms of Figure 7, it can be seen
                                                                that in the case of the non-reinforced samples, plastic
                                                                deformation dominates, and failure of the specimens
                                                                occurs under quasi-constant energy absorption, typically
                                                                with disruption. By contrast, in the case of the composites,
                                                                the impact load increases linearly with time until fracture
                                                                and the triangle-shape fractogram indicates rather rigid
                                                                behaviour. After fracture initialization, a slight plastic
                                                                zone can also be observed, likely due to the disruption
                                                                of the elastomer matrix. Failure of composites occurs
                                                                typically within 8 ms compared with the 14 ms of the
                                                                non-reinforced plates. The adverse consequences of the
                                                                fibre damage of the 15% FR containing composite are also
          Comparison of the stress‐strain curves of injection moulded flame   visible based on this test, and failure of the SR-PP_FR15
          retarded non‐reinforced and self‐reinforced PP samples   composite occurs at significantly lower impact load than

          In our system, the homopolymer fibres did not aggregate   the other self-reinforced composites.
          and could maintain their mechanical performance during   Figure 7
          processing and thus serve as adequate reinforcement in
          the composite. Furthermore, suitable adhesion could be
          formed between the hPP fibres and the ePP matrix even
          when 10% FR was added. The 15% FR containing composite,
          however, showed weaker mechanical performance, and
          its  tensile  strength  deteriorated by  50%  and  tensile
          modulus by 15%, respectively, compared with the SR-PPC
          of lower FR content, likely due to the structural damage
          of the reinforcing fibres occurred during the composite
          preparation and thermo-mechanical processing.

          Figure 6










                                                                Comparison of the impact load‐time curves of injection moulded
                                                                flame retarded non‐reinforced and self‐reinforced PP samples
                                                                The  calculated  perforation  energy  and  ductility  index
                                                                values are shown in Figure 8A,B, respectively. It can be
                                                                seen that the perforation energy of the composites is
          Comparison  of  the  (A)  tensile  strength  and  (B)  tensile  modulus  of   approximately 50% of that of the non-reinforced samples;
          injection moulded flame retarded non‐reinforced and self‐reinforced   furthermore, the 15% FR containing composite reached
          PP samples                                            only 30% of the perforation energy of the ePP sample of
                                                                identical FR content. The impact damping capability of



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