Page 68 - Plastics News November 2018
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teChnoLogy



         Breakthrough in self-healing materials



             he cost of making plastics, paints, coatings for   about his latest breakthrough is that if a company wanted
          Tcell phone screens and other materials that heal     to bring the technology to market, it would no longer have
          themselves like skin could be dramatically reduced thanks   to build a new factory to produce self-healing polymers,
          to a breakthrough that a Clemson University team detailed   Urban said. Urban estimated that increasing the scale to
          in the latest edition of the journal Science. Marek Urban   make polymers or paints by the hundreds of gallons could
          and his team wrote about how they were able to give self-  be done in six to 12 months.  "For anybody who wants to
          healing qualities to polymers that are used in relatively   make these types of self-healing materials, they would
          inexpensive commodities, such as  paints,  plastics  and   have to essentially design a synthetic process and scale
          coatings. The next step is to go from making small amounts   it up," Urban said. "
          in a lab to producing large quantities. "It's not available
          at the industrial scale, but it's very close," said Urban,
          who is the J.E. Sirrine Foundation Chair and Professor in   The Cora ball to reduce marine
          the Department of Materials Science and Engineering at
          Clemson.Researchers have been making small batches     pollution
          of self-healing  polymers for the  last  two  decades,  but
                                                                    oncern is mounting over the volume of plastics in our
                                                                 Coceans and, in particular, how Can technology help
                                                                 address the problem of tiny particles of plastic and other
                                                                 synthetic materials  that re infiltrating every part of our
                                                                 ecosystem and the and the answer is yes .  Ms Miller,
                                                                 who had studied marine archaeology, decided to devote
                                                                 herself to keeping plastics from ever reaching the ocean
                                                                 . She began designing and selling a special gadget for
                                                                 capturing those tiny bits of synthetic material - called
                                                                 microfibres - that come off our clothes in the wash.Four
                                                                 inches (10cm) in diameter and made from recycled and
                                                                 recyclable plastic, the Cora Ball imitates the structure
                                                                 of coral in the ocean. While it doesn't catch everything,
                                                                 the company says it captures between a quarter and a
                                                                 third of microfibres
          producing them on a commercial scale has so far been
          largely cost prohibitive. Urban said he and his team took   in every wash.
          advantage of interactions between co-polymers that he   Cora Ball is one of
          likened to spaghetti strands with little brushes on the   several small start-
          side. The longer the spaghetti strands get, the more they   ups working to keep
          become entangled, he said. The side groups interlock   microplastics  and
          like two interlaced hands, making it harder to pull them   other microfibres out
          apart, Urban said. "At the same time, they like each other,"   of the water system.
          he said. "So, when you pull them out, they come back   The shocking truth
          together. It becomes self-healable at that point.      is that we could be
                                                                 ingesting 11,000
          "As simple as this may sound, these studies also revealed   pieces of plastic a year just through eating shellfish,
          that  ubiquitous  and  typically  weak  van  der  Waals   says Ghent University's Lisbeth Van Cauwenberghe. It's a
          interactions in plastics, when oriented, will result in self-  pollution we all contribute to when we wash our clothes.
          healing. This discovery will impact the development of   If just 10% of US households used Cora Ball it would keep
          sustainable materials using weak bonding which becomes   the equivalent of 30 million water bottles from washing
          collectively very strong when oriented."  What's significant   into public waterways a year, claims Rachael Miller.



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