Page 22 - Plastics News July 2021
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          The method dubbed GIMIM entails the addition of gas traps at each stage of molding, various plasticization
          stages

             ngineering thermoplastics supplier Polyplastics    Polyplastics lays out the negative cycle offgassing can
          EKDV  GHYHORSHG  D  WHVWLQJ  PHWKRG  WKDW  LGHQWLÀHV  JDV   create where the presence of mold deposits, gas burns
          formation during injection molding and ultimately can   and short shots leads to the installation of larger vents on
          help reduce mold deposits.                            WKH WRRO  7KHVH ODUJHU YHQWV FDQ OHDG WR ÁDVKLQJ  IRUFLQJ
                                                                the vents to be reduced in size, which once again creates
          Dubbed Gas Investigation Method in Injection Molding
          (GIMIM), the concept entails the addition of gas traps   gas issues within the tool.
          at each stage of molding: plasticization, metering, and   GIMIM makes it possible to measure high-molecular-weight
          injection. Once captured, gas chromatography mass     substances that can cause mold deposits. Since this
          spectrometers (GC/MS) are used to qualitatively and   method directly analyzes gases that are formed inside the
          quantitatively analyze the gases produced in the various   PROG GXULQJ ÀOOLQJ  WKH FRPSDQ\ EHOLHYHV LW \LHOGV UHVXOWV
          plasticization stages.                                that are closest to real-world conditions.
                                                                Prior to GIMIM, ascertaining the source and output of
                                                                pyrolysis gas largely fell to two methods, neither of which
                                                                captured the actual conditions in the tool. One method
                                                                involved heating pellets and analyzing the resulting
                                                                volume and composition of decomposition gases. The
                                                                other technique involved running a tool and material and
                                                                then analyzing the resulting mold deposits that adhered
                                                                to the mold.
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                                                                and chemical adsorption where in the former mold
                                                                deposits are adsorbed to positively charged metal surfaces
                                                                and in the latter electrons are shared between surface
          The high speeds, temperatures and pressures of injection   layer atoms in covalent bonds and hydrogen bonds. In
          molding can lead to the deterioration of plastic additives   further research, Polyplastics plans to examine other
          and the subsequent release of decomposition gases. Mold   problems caused by pyrolysis gas such as short shots and
          deposits, gas burns, and short shots caused by pyrolysis   gas burn defects, as well as mold deposits.
          gas create quality issues and higher defect rates.


          bubble expanded and even made a pop when it burst.    7KH ÀUVW VWHS LQ WKH SURFHGXUH LV WR WDNH RII KROG RU VHFRQG
          *DV  EXEEOHV  PD\  VWHP  IURP  ÁRZ IURQW  LVVXHV   VXFK  DV   stage by adjusting the hold pressure down to a very low
          converging fronts, jetting, or mold/machine problems
          such as non-vented core pins, poor venting (try vacuum
          venting), too much decompression, or resin degradation
          due to overheating or long residence times.

          The gas may appear from water vapor, volatiles from
          the resin, or decomposition byproducts. Air trapped in
          ribs or non-vented projections off the nominal wall will
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          of bubbles. Determining where the gas is coming from is
          more important than knowing the composition of the gas,
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