Page 51 - Plastics News April 2022
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TECHNOLOGY







                            New Polymer Membrane Tech Improves Efficiency


                                             cause CO2/nitrogen dioxide mixtures  situation in which one needs to remove
                                             are particularly relevant in the context  CO2 from mixed gases -- whether it's
                                             of  reducing  greenhouse  gas  emissions  a biomedical application or scrubbing
                                             from power plants," says Rich Spontak,   CO2 from the air in a submarine." "In
                                             co-corresponding author of a paper on   short, with little change in permeability,
                                             the work. "And we've demonstrated   we've demonstrated that we can increase
                                             that we can vastly improve the selectiv-  selectivity by as much as about 150
                                             ity of membranes to remove CO2 while   times," says Marius Sandru, co-corre-
                                                                                 sponding author of the paper and senior
             esearchers from the North Caro-  retaining relatively high CO2 perme-  research scientist at SINTEF Industry,
          Rlina State Universityhave developed   ability." "We also looked at mixtures of   an independent research organization
          a new membrane  technology that al-  CO2 and methane, which is important   in Norway. "So we're capturing much
          lows for more efficient removal of car-  to the natural gas industry," says Spon-  more CO2, relative to the other species
          bon dioxide from mixed gases, such as   tak, who is a Distinguished Professor of   in gas mixtures." Our next steps are to
          emissions from power plants and ap- Chemical and Biomolecular Engineer-  see the extent to which the techniques
          plication of  this  technology could be  ing and Professor of Materials Science  we developed here could be applied to
          highly helpful in Chemical and further  & Engineering at North Carolina State  other polymers to get comparable, or
          biomedical    applications.  We  looked  University. "In addition, these CO2- even superior, results; and to upscale the
          at mixtures of CO2 and nitrogen, be- filtering membranes can be used in any  nanofabrication process," Sandru says.




                 Enhancing The Electromechanical Behavior Of A Flexible Polymer


                                             out to improve this because the relative  from 10% efficiency before."  This ro-
                                             softness of polymers makes them ex- bust  electromechanic  performance,
                                             cellent candidates for soft sensors and  which is more common in stiff ceramic
                                             actuators in a variety of areas, includ- materials, could enable a variety of ap-
                                             ing biosensing, sonar, artificial muscles  plications for the flexible polymer. This
                                             and more." To create the material, the  could be applied for use in medical im-
                                             researchers deliberately implemented  aging, underwater hydrophones or pres-
                                             chemical impurities into the polymer.  sure  sensors.  Polymers  also  tend  to  be
                                             This process, known as doping, allows  more lightweight and configurable than
                                             researchers to tune the properties of a  ceramics, so this polymer could pro-
              iming Zhang, distinguished pro- material to generate desirable effects  vide opportunities to explore improve-
          Qfessor  of  electrical  engineering  -- provided  they integrate the correct  ments in imaging, robotics and more,
          and  a Pennislyvania State-led team of  number of impurities. Adding too little  Zhang said. Other contributors to this
          interdisciplinary researchers developed a  of a dopant could prevent the desired  work include Xin Chen, with the Pen-
          polymer with robust piezoelectric effec- effect from initiating, while adding too  nyslyvania State Department of Ma-
          tiveness, resulting in 60% more efficient  much could introduce unwanted traits  terials Science and Engineering in the
          electricity generation than previous it- that hamper the material's function.The  College of Earth and Mineral Sciences;
          erations.  They  published  their  results   efficiency of the polymer's electricity  Hancheng Qin, Bing Zhang, Wenchang
          in Journal of Science. "Historically, the  generation was vastly increased," Zhang  Lu and J. Bernholc with North Caro-
          electromechanics coupling of polymers  said. "With this process, we achieved a  lina State University; Xiaoshi Qian with
          has been very low," Zhang said. "We set  70% efficiency -- a vast improvement  Shanhai Jiao Tong University in China.



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