Page 32 - Plastcs News August 2017
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FEATurES
        FEATurES



          INTRODUCTION

          Waterborne clear coatings have been developed to meet   without SB1 pretreatment. Furthermore, data also
          those requirements and address the concerns of high VoC   suggested that by increasing the coating thickness, the
          that are normally associated to conventional solvent-  light fastness of Southern Pine can also be improved to
          based coatings [1]. Most customer use waterborne clear   some degrees but not as effective as other methods such as
          wood coatings to protect wood materials. However,     increasing the use level of light stabilizers in the clear coat
          sunlight  and  UV  radiation  can  penetrate  coating  into   or having the pre-treatment of Southern Pine prior to the
          wood surface to cause yellowing.  The yellowness is   application of clear coat [9]. Lignin is a complex organic
          included coating and lignin. Wood is composed of lignin,   polymers. The functional group contains hydroxyl groups
          cellulose and hemicelluloses. Lignin, when exposed to   (-oH). The different solubility parameter of co-solvents
          the sunlight, can easily be degraded [2-6]. The routed   mixed with SB-1 and then pretreated on wood surface.
          of photodegradation of lignin [7-8] is shown in Figure 1.   How performance with different solubility parameter?
          Eversorb AQ-1 is waterborne light stabilizer. Eversorb SB1,   The softwoods contain 25–35% lignin and hardwoods
          designed for wood pretreatments. Test data confirmed   contain 18–25% lignin [10]. Theory, SB-1 pre-treatment is
          that by increasing the concentration of AQ-1 in the clear   significant to protect softwoods.
          top coat can effectively protect Southern Pine from UV
          light degradation. However, when Southern Pine was is   The subject of this paper is to demonstrate the use of 5
          pre-treated with SB-1 prior to the application of the same   types of wood. Softwoods (Southern Pine and Douglas fir)
          clear top coat, the weatherability is better than the one   and hardwoods (Cedar, Southern beech and African Teak)
                                                                are test in this model.
























                                              Fig. 1. Route d of photodegradation of lignin






          EXPERIMENT
         The three model formulations used in this study were an acrylic based waterborne clear coating, wood pretreatments
         and co-solvents. Their detail compositions are shown in Table 1, Table 2 and Table 3. The 5 varied Woods were chosen
         in the region are shown in Figure 2. Design of Experiment (DoE) was used to design test runs as well as to analyze test
         data. DoE technique allows us to validate the data.




        Plastics News | August  2017  32
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